We make volume phase holographic gratings (VPHGs) recorded interferometrically in DiChormated Gelatin (DCG) sealed in glass. While there are many other optical recording media, DCG possesses the required combination of characteristics to produce very low polarization dependent loss (PDL), very high efficiencies, and wide bandwidths. These translate into benefits that enable telecom and other companies to leverage and capitalize on their own technologies.
VPHGs, have a constant thickness (T) with a periodic, typically sinusoidal, change in refractive index (n). Surface relief gratings have a periodic change in thickness with a constant refractive index. Most VPHGs are made in transmission geometry while most surface relief gratings are made in reflection geometry. Master VPHGs can usually be made for spatial frequencies >900 lpmm. These master VPHGs may be copied optically without either the master or copy VPHG degrading over time. Since surface relief masters are copied mechanically, both the surface relief master and copy will degrade over time as the number of copies increases.
VPHGs possess low stray light and low absorption in the visible and NIR. They are sealed in glass making them long-lived, easy to handle, scratch resistant, and easy to clean. VPHGs usually have anti-reflection (AR) coatings applied to one or both surfaces to minimize Fresnel reflections and increase overall output.
VPHGs, whether they are AR coated or not, can be easily be cleaned just as you would any other glass optic to remove fingerprints, dust, and contaminants. Use the standard optics cleaning method of “drop and drag”. Gently wipe the grating with a clean, lint-free cloth/wipe using acetone or alcohol without much pressure; reagent-grade methanol or Windex may also be used. Do not use MEK, polishing compounds, etc. Hard rubbing with such chemical or polishing compounds may damage the AR coating. AR coated surfaces will pass the “Scotch Tape” test.
Our gelatin recording medium is very similar to the gelatin that has been used in the photography industry for more than 100 years. As you may know, properly processed photographs are very stable and will retain their properties for decades. One of the major reasons for this excellent stability of photographs is the stability of the gelatin base. The discoloration of very old black and white photographs is a result of insufficient removal of fixer from the paper base, which results in a yellowing of the paper. It has nothing to do with the gelatin.
Wasatch Photonics uses a dichromated gelatin (DCG) mixture as its recording medium of choice. Once this mixture is processed and the chromium removed, it is essentially pure gelatin and is very stable. During the past thirty years, there has been no measurable degradation in gelatin gratings that are properly sealed. The DCG holographic scanning disks used in some of the early optical bar code scanners still function exactly as they did over 20 years ago.
A Dickson Grating® is a highly specialized volume phase transmission grating. It can diffract both orthogonal linear polarizations with equal and high efficiency at included angles greater than 90 degrees over 40 nm bandwidths. Other gratings designed to be used at these high diffraction angles will have much greater PDL, lower diffraction efficiency, and a greater variation in diffraction efficiency across a 40 nm bandwidth. The 40 nm bandwidth and favorable high dispersion angles combined with efficiencies near 95% make the Dickson Grating® highly desirable for Telecom applications such as Mux/Demux/Remux, OSA, monitors, filters and Raman Spectroscopy. The grating is named after the grating designer, and Wasatch Photonics Co-Founder, Lee Dickson.
Dickson Gratings® can easily be designed for almost any spectral range. For instance, a 940 lpmm Dickson Grating® designed for 1525-1565nm will have these high performance characteristics:
- High Dispersion
- Extremely High Efficiency (>90%)
- Extremely Low PDL (<0.25dB)
- Flat Response Across C, S, or L Bands
VPHGs can be made at almost any angle. Dickson Gratings® perform in narrow angular ranges, it is this limitation that allows them to work as well as they do. There are however two classes of realizable Dickson Gratings® with the first working near a half angle of 46.5 degrees in air and the other working at internal angles too high to escape from a flat substrate which must therefore be used with prisms. This latter design is termed the Dickson Grism® and has nearly TWICE the dispersion per pass of a Dickson Grating®. In January of 2005, we delivered samples of our latest high dispersion product, the Dickson 1350® for 1525-1565nm which produces >2 times the dispersion of a 940 lpmm Dickson Grating®.
We cover 350 – 2400 nm (the entire visible range and NIR) with a selection of glass substrates and prisms.
Typical ruggedized sizes with perfect hermetic seals begin at approximately 20 mm x 30 mm. Smaller sizes have to be externally sealed. Gratings as large as 400 mm x 400 mm have been made by the Wasatch Photonics team.
1/4 wave is typical. Wavefront uniformity very low wavefront error Dickson Grating®.
Our telecom-grade, epoxy sealed gratings have survived boiling water for several days with no degradation and 95° C at saturated humidities for more than 2 weeks. A collapse of the grating structure has been observed after several days at 120° C. Some of our similar, but non-Dickson design, gratings are currently in commercial multiplexers and are surviving real world tests as well as having passed standard compliance testing. The DCG is hermetically sealed between various substrates such as BK-7, Borofloat, low iron sheet glass and fused silica, making it impervious to everything but extreme heat.
Aiming stability over time and temperature is completely dependent upon the substrate used. Near zero drift is obtained by using a substrate with a low thermal coefficient of expansion (TCE) such as fused silica.
There is hardly any absorption in a phase grating. The more common reflection gratings absorb as much as 20% and get really hot. It is not uncommon for communication signals to be between 5 and 50 mw, so adding up a hundred or more channels is a lot of heat. The gratings can take the heat but the losses at the fiber ends will be measured in watts, so heat dissipation probably has to be considered in a device’s package. Total absorption and scatter in the grating is about 2 or 3% so it is not a problem. Depending upon the glue, it can begin to soften or degrade between 10 to 100 watts per square cm continuous wave. Properly hardened gelatin can withstand >100 watts per square cm continuous wave. Peak power from pulsed laser energy applications can have energy densities in the megawatts.
Test results over a temperature range of 0-100o C indicate no significant change in efficiency, <0.5%, for a typical Dickson Grating®. Gratings can also withstand repeated temperature cycling with no measurable degradation in performance.
The effect of high energy radiation on gelatin is also important to anyone intending to put DCG hoes into space or into solar collectors outdoors or into creative lighting designs in buildings where the windows are DCG gratings. Gelatin, like all organic and many inorganic substances will be damaged by photons of more than 4 or 5 electron volts. Eventually all the bonds will be broken if the flux and energy are high enough for long enough. The gel will then be decomposed into loose atoms and molecules incapable of maintaining the original physical form. Fortunately the process takes a very long time to complete, if the gel is protected between two pieces of glass.
We have tested holographic scanners sandwiched between two pieces of 1.5 mm thick glass by placing them near a 250 watt low pressure mercury arc lamp for over 24 hours or until the glass itself solarized and became dark near the exposed surface. The gelatin was unchanged in diffractive properties but the glue line and the gel were slightly yellowed which would reduce transmission in the blue region. Less severe tests on display holograms were carried out from 1977 to 1979 where the test pieces were placed out in the open to take on whatever the weather in Salt Lake city and also in New Jersey could dish out. In all cases, for a year or for a month, the glue that we were using then became noticeably yellow but the gelatin and glass remained unchanged within the limits of our ability to measure it optically.
Another test was carried out on DCG and three other recording materials that were all prepared in our Paradise lab in 1989 for Northrop electronics division. Several Sample gratings were recorded on thick fused silica substrates and then baked and capped with another silica plate. This time the wave-fronts were measured and photographed before and after the radiation treatments. Neither the efficiency or any other property of the hologram changed from high energy radiation equivalent to several years of direct exposure in space. Somewhere a formal report exists to back up this statement but it did not yield to my searches and the individuals that carried out the work are no longer at Northrop. They did send me some photographs of the wave-fronts and I have those but they cannot tell me what the radiation doses were. In this case the silica could not absorb much of the radiation so it was a truer test of the durability of the gelatin itself. A few of our customers have put our large gratings into green houses as panes of glass and they appear to have survived at least since 1986 or so. Several 16 inch diameter hoes have gone to NASA Goddard where they are used in outdoor LIDAR since about 1991. One early reflection hoe which was not baked out has drifted a little to the blue, nothing that was baked thoroughly before sealing has changed. – By Richard Rallison
We have developed novel techniques that significantly reduce variations in diffraction efficiency across our gratings.